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It is négative as we havé calculated (and prédicted from the réaction being two gasés going to á solid).But how cán we evaluate thé entropy change causéd by dumping 176 kJ mol -1 of heat energy into the surroundings (Notice that this is 176 000 J mol -1.) It must be positive as more quanta of energy lead to more possible arrangements and it must be more than 284 J K -1 mol -1.Interpreted in this way, Boltzmanns formula is the most general formula for the thermodynamic entropy.For this casé, the probability óf each microstate óf the systém is equal, só it was equivaIent for Boltzmann tó calculate the numbér of microstates associatéd with a macrostaté.
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